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Chemical geothermometry in geothermal systems
Authors:AJ Ellis
Institution:Chemistry Division, DSIR, Petone New Zealand
Abstract:The application of chemical and isotopic geothermometry to geothermal systems is reviewed, pointing out the uses and limitations of specific reactions in estimating deep temperatures from well, hot-spring and fumarole discharges.At present the most reliable indicators are: the silica-water equilibria; the Na/K ratio; the isotopic distributions Δ2H(H2“H2O), Δ2H(H2“CH4), Δ18O(H2O“HSO?4); and the gas reactions CO2 + 4H2 ? CH4 + 2H2O, and 2NH3 ? N2 + 3H2. Many other qualitative chemical indicators exist.
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