Abstract: | Abstract Abstract Stream sampling programmes for water quality estimation constitute a statistical survey of a correlated population. The properties of parameter and other estimates made from sample values from such programmes are set in the context of statistical sampling theory. It is shown that a model-based rather than a design-based approach to statistical analysis is usually appropriate. The influence of model structure and sampling design on the robustness and suitability of estimation procedures is investigated, and relationships with kriging are demonstrated. Methodology is discussed with reference to data from a UK sampling programme |