Combustion Kinetics of Athabasca Bitumen from 1D Combustion Tube Experiments |
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| Authors: | Xiaomeng Yang Ian D Gates |
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| Institution: | (1) Department of Chemical and Petroleum Engineering and Alberta Ingenuity Centre for In Situ Energy (AICISE), Schulich School of Engineering, University of Calgary, Calgary, AB, Canada |
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| Abstract: | There are two basic requirements for heavy-oil recovery processes: first, mobilize the bitumen, and second, have a drive mechanism
deliver the mobilized bitumen to a production wellbore. In situ combustion has the potential to be an important heavy-oil
recovery method. Before design of in situ combustion recovery processes can start, it is necessary as a first step to understand
the kinetics of various complex chemical reactions and determine kinetic constants associated with the reactions. Even with
modern reservoir simulation capabilities, this is a significant challenge. In this research, an Athabasca bitumen combustion
tube experiment, conducted by the ISC Research Group at the University of Calgary, was history matched by using a reservoir
thermal simulator to determine a set of kinetic parameters as well as the transport parameters for the system. The main results
of the history match was a match of air injection rate, bitumen and gas production volumes, average product gas compositions,
temperature profiles along the tube through time, and pressure. Gridding sensitivities were examined to determine if the derived
kinetic and transport parameters were dependent on gridblock size. The results revealed that the grid was refined enough to
sufficiently capture thermal, mass transfer, and reaction length scales. After this single match was achieved, the same constants
were used to successfully predict several other combustion tube experiments. The results suggest that the fuel (coke) for
high-temperature oxidation (HTO) originates mainly from low-temperature oxidation (LTO) and not from thermal cracking. This
implies that the major control on HTO is upstream oxygen transfer into the LTO region. If LTO does not occur, then a relatively
small amount of coke is deposited in the matrix due to thermal cracking and this may be insufficient to start or sustain HTO. |
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| Keywords: | In situ combustion combustion tube combustion kinetics enhanced oil recovery Athabasca bitumen |
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