Potentiometric Determination of Silver Thiolate Formation Constants Using a Ag2S Electrode |
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| Authors: | Nicholas W H Adams James R Kramer |
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| Institution: | (1) School of Geography and Geology, McMaster University Hamilton, Ontario, Canada, L8S 4M1 |
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| Abstract: | Formation constants for silver thiolates were obtained by titration of the ligand in a constant temperature, ionic strength and pH medium and measuring the potential change at a Ag2S electrode. A non-linear equation was derived from which the first and second silver formation constants,  1 and 2 , and the sulfide group acid dissociation constant, Ka, were determined. An overall estimate of the uncertainty in the derived parameters was obtained using a Monte Carlo approach. The procedure was compared to a previous work on AgHS°. Log 1, log 2 and - log Ka results were obtained for cysteine (11.9 ± 0.5, 15.2 ± 0.4, 7.8 ± 0.1), glutathione (12.3 ± 0.3, 14.3 ± 0.8, 8.8 ± 0.3) and 3-mercaptopropanoic acid (12.0± 0.4, 14.0 ± 0.4, 10.5 ± 0.3) at 20 °C and 0.01 m ionic strength. |
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| Keywords: | Silver sulfide thiols formation constants |
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