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日本的海水化学资源提取技术研究
引用本文:蔡邦肖.日本的海水化学资源提取技术研究[J].海洋学研究,2000,18(4):52-56.
作者姓名:蔡邦肖
作者单位:国家海洋局杭州水处理技术研究开发中心!浙江杭州310012
摘    要:海水化学资源例如铀、锂提取技术已进入海水现场小规模试验。以纤维状偕胺肟类化合物为吸附材料 ,每公斤吸附剂的提铀量为 1 g。添加质量分数为 2 0 %聚氯乙烯的尖晶石型锰氧化物粒状海水提锂吸附剂 ,每克吸附剂的提铀量为 1 8mg。浮体式吸铀装置可用于深海作业。流动床或船舶提锂系统 ,可规模化海水提锂。吸锂剂的脱附以及脱锂液的浓缩分离已初步达到小型生产的程度。用吸附法从海水中提取的碳酸锂纯度达 99%以上 ,海水锂回收率为 2 7%。

关 键 词:海水  化学资源  吸附剂      环状化合物  偕胺肟  锰氧化物

Extraction of chemical resources in sea water in Japan
CAI Bang\|xiao.Extraction of chemical resources in sea water in Japan[J].Journal of Marine Sciences,2000,18(4):52-56.
Authors:CAI Bang\|xiao
Abstract:The techniques to extract uranium and lithium in the sea water have come to small\|scale on the spot test stage. When fiber\|shape amidoximes compounds are used as adsorbent, the quantity of extracted uranium from sea water is 1 g per kg adsorbent. If the granular lithium adsorbent of spinel type manganese oxide with 20% PVC is added the extracted uranium is 18 mg per gram adsorbent. A floating type uranium\|adsorbing device can be used in deep sea; and the floating bed or ship lithium\|extracting system can be used for extracting lithium in a big volume. The desorption of the lithium adsorbent and the concentrated separation of lithium\|removing liquid have attained a small\|scale production stage. The purity of lithium carbonate extracted from the sea water by adsorption method is up to over 99% and the recovery rate of lithium in sea water is 27%.
Keywords:sea water  chemical resources  adsorbent  uranium  lithium  expoxide  amidoxime  manganese oxi  
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