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POTENTIOMETRIC TITRATION OF CALCIUM IN SEAWATER
作者姓名:谢式南  纪红  吴爱琴  陈国华
作者单位:Department of Marine Chemistry,Qingdao Ocean University,Qingdao 266003
摘    要:Atpasent,thestandardmethodfordetendningcalciuminseawateriscomPlexometrictitrationusingEGTAethyleneglycol-bis(2-adrinoethylether)-N,N,N',N'-tetraaceticacid]andGHAtelyoxal-bis(2-hydroxyanil)].ThisInethodwasfirStdeveopedbyTSunogaietal.(l968),sumrnarindbyKremling,andeditalinMethodsofSeawaterAnalySisbyGrasshoff(l983).AlthoughtheendpointreadingsinthismethodarenotquitCsharp,andrnaybeaffCCtedbyoveanstweather,withtheuseofcalctumISEasindicatingeledrode,SCEasreferenceeledrodeanddigitalvoltme…

收稿时间:22 September 1995
修稿时间:14 June 1996

Potentiometric titration of calcium in seawater
Xie Shi-nan,Ji Hong,Wu Ai-qin,Chen Guo-hua.POTENTIOMETRIC TITRATION OF CALCIUM IN SEAWATER[J].Chinese Journal of Oceanology and Limnology,1997,15(1):32-35.
Authors:Xie Shi-nan  Ji Hong  Wu Ai-qin  Chen Guo-hua
Institution:(1) Department of Marine Chemistry, Qingdao Ocean University, 266003 Qingdao
Abstract:By using calcium ion selective elatrode (Ca ISE) as indicating electrode, saturated calomel electrode (SCE) as reference electrode and EGTA as titrant, calcium in seawater was determined by potentiometric titration in borate buffer solution. This method can reduce observation errors in the determination of the endpoint, and thus provide better analytical precision(<0.08%) than present complexometric titration.
Keywords:calcium ion selective elatrode  calcium  seawater  potentiometric titration
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