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钙基液态水硬性加固剂用于潮湿土遗址的加固保护
引用本文:魏国锋,张秉坚,杨富巍,胡宝忠,陈兵,王旭东.钙基液态水硬性加固剂用于潮湿土遗址的加固保护[J].岩土力学,2012,33(3):702-712.
作者姓名:魏国锋  张秉坚  杨富巍  胡宝忠  陈兵  王旭东
作者单位:1. 浙江大学 文物与博物馆学系,杭州 310027;2. 安徽大学 历史系,合肥 230039;3. 敦煌研究院,甘肃 敦煌 736200
基金项目:国家科技支撑计划资助项目(No.2010BAK67B16);浙江省文物保护专项(浙财教[2010]264号);中国博士后科学基金资助项目(No.20100471728)
摘    要:通过对钙基液态水硬性加固剂的研制,对潮湿环境土遗址的加固保护进行了探索性研究。X射线衍射(XRD)和扫描电镜(SEM)分析结果表明,已成功制出了潮湿土样水硬性加固所需的纳米材料。同时,研究发现,氢氧化钙在650 ℃下用马弗炉煅烧1.5 h后,可得到直径约50 nm、长度约200 nm的针状二次生石灰;这种二次生石灰经水消化后,会成为粒径在200~300 nm左右、大小十分均匀的扁平椭圆状纳米氢氧化钙颗粒;氧化钙在密封陈化一段时间后,也可使氢氧化钙的粒径达到纳米级。土样加固试验的结果显示,纳米石灰的乙醇分散液的渗透性优于分析纯氢氧化钙,钙基水硬性加固剂对潮湿土样的加固效果较为明显,有望成为一种适合于潮湿环境土遗址加固的新型材料。

关 键 词:土遗址  潮湿环境  水硬性  加固
收稿时间:2010-10-08

Consolidation of historical earthen sites under moisture circumstance using calcium-based hydraulic consolidant
WEI Guo-feng , ZHANG Bing-jian , YANG Fu-wei , HU Bao-zhong , CHEN Bing , WANG Xu-dong.Consolidation of historical earthen sites under moisture circumstance using calcium-based hydraulic consolidant[J].Rock and Soil Mechanics,2012,33(3):702-712.
Authors:WEI Guo-feng  ZHANG Bing-jian  YANG Fu-wei  HU Bao-zhong  CHEN Bing  WANG Xu-dong
Institution:1. Department of Cultural Relics and Museology, Zhejiang University, Hangzhou 310027, China; 2. Department of History, Anhui University, Hefei 230039, China; 3. Dunhuang Academy, Dunhuang, Gansu 736200, China
Abstract:On the basis of preparation and characterization of calcium-based hydraulic consolidant,this paper makes a preliminary study of consolidation conservation of historical earthen sites under moisture circumstance.Analytic results of scanning electron microscope and X-ray diffractometry show that Ca(OH)2 are transformed into a kind of acicular secondary CaO with diameter 50 nm and length 200 nm after being calcined,and this nano-sized secondary CaO are transformed into oval plate-like Ca(OH)2 with size 200-300 nm after being slaked.Meanwhile,research results indicate that calcium hydroxide crystals undergo both substantial size reduction and clear morphological change,developing nanometer,plate-like and acicular crystals upon aging.Results of consolidation experiment of moist earthen samples reveal that permeabilities of nanometer lime-alcohol dispersions are superior to that of analytically pure Ca(OH)2-alcohol dispersions,and consolidation effects of calcium-based hydraulic consolidant are obvious.It is possible that calcium-based hydraulic consolidant will become a new consolidation material used for conservation of historical earthen sites under moisture circumstance.
Keywords:historical earthen sites  moisture circumstance  hydraulic  consolidation
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