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Absorption and Photocatalytic Degradation of Machine Oil by Exfoliated Graphite-Supported Nanometer TiO2 Material
作者姓名:CAO  Hong  MA  Enbao  WANG  Xuehua  CHEN  Jiazang  BIN  Xiaobei
作者单位:[1]School of Materials Science & Engineering, Wuhan Institute of Technology, Wuhan, Hubei 430074 [2]State Key Laboratory of Green Chemistry Synthetic Technology, College of Chemical Engineering & Materials Science, Zhejiang University of Technology, Han
基金项目:Hereon, we wish to thank the 0utstanding Young and Middle-aged Teacher Project of the Education Department of Hubei (Grant No. 2003B001), and Miss Li Lei for finishing all of infrared spectrum test.
摘    要:By loading nanometer anatase onto exfoliated graphite with the sol-gel method, exfoliated graphite-TiO2 composite (EG-TiO2) can be prepared, which can adsorb oil and can also degrade oil. In a technologic condition for preparing EG-TiO2, the impregnated number of times is the most important factor to influence oil-adsorbing capability, that is, when the impregnated number of times increases, the amount of saturation-adsorbed oil decreases. The study of EG-TiO2 photocatalytic degradation of machine oil based on the weight-loss method and infrared spectrum method indicates that EG-TiO2 has obvious effect of photocatalytic degradation for machine oil. Its performance is superior to pure nanometer TiO2 powder because nanometer TiO2 in EG-TiO2 has three-dimension laminar structure and comparatively high adsorption capability.

关 键 词:石墨  二氧化钛  光催化作用  降解作用
收稿时间:2006-01-11
修稿时间:2006-02-17

Absorption and Photocatalytic Degradation of Machine Oil by Exfoliated Graphite-Supported Nanometer TiO2 Material
Authors:CAO;Hong;MA;Enbao;WANG;Xuehua;CHEN;Jiazang;BIN;Xiaobei
Abstract:By loading nanometer anatase onto exfoliated graphite with the sol-gel method, exfoliated graphite-TiO2 composite (EG-TiO2) can be prepared, which can adsorb oil and can also degrade oil. In a technologic condition for preparing EG-TiO2, the impregnated number of times is the most important factor to influence oil-adsorbing capability, that is, when the impregnated number of times increases, the amount of saturation-adsorbed oil decreases. The study of EG-TiO2 photocatalytic degradation of machine oil based on the weight-loss method and infrared spectrum method indicates that EG-TiO2 has obvious effect of photocatalytic degradation for machine oil. Its performance is superior to pure nanometer TiO2 powder because nanometer TiO2 in EG-TiO2 has three-dimension laminar structure and comparatively high adsorption capability.
Keywords:exfoliated graphite  nanometer TiO2  photocatalysis  degradation  machine oil
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