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Accessory phases and the generation of LREE-Enriched basalts — A test for disequilibrium melting
Authors:Ian H Campbell  Michael P Gorton
Institution:(1) Department of Geology, University of Toronto, M5S 1A1 Toronto, Canada
Abstract:The REE contents of tholeiitic rocks can be derived by simple mantle melting models. However this type of model has been less successful in accounting for rocks of the alkali basalt-kimberlite suite with strong LREE enrichment. Rocks from these associations have similar La/Sm ratios over a range of total REE concentrations and their generation by simple melting models requires an enriched source. These requirements conflict with the conclusions reached from Nd-Sm studies.An alternative hypothesis involves the disequilibrium melting of a LREE-rich accessory phase in the mantle. Such a phase will be among the first to melt and thus will dominate the REE patterns of early-formed liquids, even if subsequent partial re-equilibration occurs. This model could account for liquids with strong LREE enrichment and similar La/Sm ratios at different levels of total REE enrichment by partial melting of a simple chondritic mantle. Since the model predicts the existence of an accessory phase in the mantle with a REE pattern parallel to that found in strongly LREE-enriched magma, it provides a sensitive test for disequilibrium melting.
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