Biogeochemical factors influencing the residence time of microconstituents in a large tidal estuary, Delaware Bay |
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| Authors: | Thomas M Church |
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| Abstract: | Generally the large tidal estuaries of the eastern United States, such as Delaware Bay, are characterized by rather high suspended particle concentrations at the landward end and high biological activity at the seaward end. As such, these estuaries can be conceptualized as geochemical and biochemical “reactors” for those processes controlling the transmission of trace elements from fresh to the coastal shelf waters. The efficiency of these reaction processes relative to estuarine flushing will control the residence times of microconstituents in such estuaries.Evidence is drawn from the Delaware estuary to illustrate biogeochemical estuarine reaction processes using salinity distribution data and mass balance calculations. The Delaware retains some of its estuarine trace elements as sedimented estuarine particles, while others are more conservative and largely exported. Those retained by sedimenting processes include trace elements in primarily geochemical (particle reactive) chemistries, while those exported appear recycled by biochemical (nutrient reactive) chemistries. Often, the behavior of trace elements (e.g., Fe, Cd) and nutrients (e.g., PO4) appear biogeochemically linked. Other examples are drawn from mixing studies to illustrate particle interaction, and benthic flux measurements to illustrate limited diagenetic reflux.The residence time of estuarine microconstituents should depend seasonally on the relative turbidity, flushing rate, and primary production of tidally dominated estuaries such as the Delaware. Thus, residence times of the more biogeochemically reactive microconstituents must be substantially shorter (days to weeks) than the average flushing times of these larger estuaries, while the residence times of the less reactive ones should approach such flushing times (weeks to months). True estuarine residence times of microconstituents can only be modeled after using large data sets averaged over time (season, tides) and space (salinity). |
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