Chemical composition of macerals in bituminous coals of the Gunnedah Basin, Australia, using electron microprobe analysis techniques |
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| Authors: | Colin R Ward Lila W Gurba |
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| Institution: | School of Geology, University of New South Wales, Sydney NSW 2052 Australia |
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| Abstract: | The chemical composition of the organic matter in the principal macerals of high-volatile bituminous coals from the Gunnedah Basin, New South Wales (Rvmax of telocollinite between 0.6 and 1.1%) has been evaluated from polished section specimens using an electron microprobe technique. Highest proportions of carbon occur in the inertinite macerals, especially fusinite and secretinite (formerly resino-sclerotinite), as well as in sporinite; lowest proportions of carbon occur in the different macerals of the vitrinite group. Oxygen shows the reverse trend, being most abundant in vitrinite and least abundant in the inertinite components, whereas sulphur is lowest in the inertinites and highest in the liptinite (mainly sporinite) present. Evaluations of maceral composition, using the carbon content of telocollinite as a rank indicator, show that carbon is more abundant in both sporinite and semifusinite, relative to vitrinite, in low-rank high-volatile bituminous coals. The difference decreases with increasing rank, and the proportion of carbon in telocollinite becomes essentially the same as that in sporinite and semifusinite at carbon contents of about 89 and 91%, respectively. The carbon content of fusinite and secretinite, on the other hand, does not seem to vary appreciably with rank advance. No significant difference in composition occurs in the rank range studied between the three vitrinite varieties present, desmocollinite, telocollinite and a more highly reflecting telocollinite resembling pseudovitrinite. No evidence was found to indicate a higher hydrogen content, relative to telocollinite, for the vitrinite matrix of desmocollinite. |
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| Keywords: | macerals electron microprobe Australia carbon oxygen sulphur |
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