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银和金的选择吸附实验研究及意义
引用本文:朱笑青,黄 艳,张 乾,何玉良.银和金的选择吸附实验研究及意义[J].矿床地质,2005,24(4):445-450.
作者姓名:朱笑青  黄 艳  张 乾  何玉良
作者单位:中国科学院地球化学研究所,贵州,贵阳,550002
基金项目:本文得到中国科学院重点创新项目(KZCX3-SW-125)及国家自然科学基金项目(编号:40H072036)的联合资助.
摘    要:吸附作用被认为是低温表生矿床的一种重要的成矿机制。文章内多种矿物对银和金的吸附实验表明,呈纳米粒级的银和金的单质对自然界矿物的吸附有明显的选择性,尤其是银对方铅矿和金对黄铁矿的强选择吸附,与自然界的实际情况符合得很好。这一实验结果为解释许多矿床中方铅矿常作为银的载体矿物及黄铁矿常作为金的载体矿物提供了科学依据。实验还证明了粘土、有机质和黑色页岩对银和金的吸附作用。

关 键 词:地球化学  吸附作用  纳米胶体溶液      实验研究
文章编号:0258-7106(2005)04-0445-06
收稿时间:2004-07-09
修稿时间:2004-07-092004-12-30

Experimental study on selective adsorption behaviors of silver and gold, and its significance
ZHU Xiao-qing,HUANG Yan,ZHANG Qian,HE Yu-liang.Experimental study on selective adsorption behaviors of silver and gold, and its significance[J].Mineral Deposits,2005,24(4):445-450.
Authors:ZHU Xiao-qing  HUANG Yan  ZHANG Qian  HE Yu-liang
Institution:Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, Guizhou, China
Abstract:Adsorption is regarded as an important metallogenic mechanism for the supergene and epithermal ore deposits. A series of experiments were made on the capabilities of a variety of minerals to adsorb silver and gold, and the results show that the nano-sized native silver and gold are strongly selective to naturally occurring minerals. It is especially notable that silver shows a strongly selective adsorption tendency toward galena and gold toward pyrite, which is in good consistency with what is observed in nature. This experimental result provides the basis for interpreting the phenomenon that galena acts as the Ag-carrier mineral and pyrite as the Au-carrier mineral in lots of ore deposits. The experiment also indicates that clay, organic matter and black shale are obviously capable of adsorbing silver and gold.
Keywords:geochemistry  admrption  nano-sized colloidal  solution  silver  gold  experimental study
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