| 基于聚二甲基硅氧烷胶与Zn-Al型水滑石复合膜为离子载体的溶解二氧化碳电极及其性能标定 |
| |
| 引用本文： | 韩沉花,潘依雯,叶瑛.基于聚二甲基硅氧烷胶与Zn-Al型水滑石复合膜为离子载体的溶解二氧化碳电极及其性能标定[J].热带海洋学报,2009,28(4). |
| |
| 作者姓名： | 韩沉花 潘依雯 叶瑛 |
| |
| 作者单位： | 浙江大学海洋科学与工程学系,浙江,杭州,310027 |
| |
| 摘 要： | 深海探测溶解CO2气体异常.可以为寻找热液口提供一个很好的证据.本文设计的基于自制的聚二甲基硅氧烷胶与Zn-Al型水滑石复合膜为离子载体的溶解CO2探测电极属于电势型CO2电极,适用于对深海中溶解形式的CO2的测量,具有体积微小、便于与pH、盐度、温度、氧化还原电位等多种传感器集成在同一探头腔内,实施在线探测等优点.实验室条件下.将该溶解CO2探测电极与银,氯化银参比电极分别接在Keithley 6517A高阻抗电位计输入端进行测试,测试结果表明:该电极对不同浓度的碳酸氢钠溶液具有良好的响应信号,响应时间大约在30s-1 min.检测限在10-1-10-4mol·L-1.
|
| 关 键 词： | 聚二甲基硅氧烷胶 Zn-Al型水滑石 复合膜离子载体 溶解CO2电极 性能标定 |
CO2 microelectrode based on Zn-Al-LDH-ion carrier and its characterization |
| |
| HAN Chen-hua,PAN Yi-wen,YE Ying.CO2 microelectrode based on Zn-Al-LDH-ion carrier and its characterization[J].Journal of Tropical Oceanography,2009,28(4). |
| |
| Authors: | HAN Chen-hua PAN Yi-wen YE Ying |
| |
| Institution: | Department of Ocean Science and Engineering;Zhejiang University;Hangzhou 310027;China |
| |
| Abstract: | A good method to find hydrothermal vents is to detect the abnormal concentration of dissolved CO2 in deep ocean.The authors have designed a dissolved CO2 microelectrode based on polydimethylsiloxane(PDMS) gel and Zinc-Aluminium-hydrotalcite(Zn-Al-LDH) ion carrier complex membrane,which can be used to detect deep-ocean CO2 abnormality.This dissolved CO2 microelectrode is miniature,and can conveniently be integrated in the same probing cavity with pH microelectrode,salinity meter,temperature sensor,oxidation-... |
| |
| Keywords: | |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
