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锂离子电池正极材料中锰、钴含量测定
引用本文:冉广芬,周园,马培华,梁窕,王亚红.锂离子电池正极材料中锰、钴含量测定[J].盐湖研究,2005,13(2):11-15.
作者姓名:冉广芬  周园  马培华  梁窕  王亚红
作者单位:1. 中国科学院青海盐湖研究所,青海,西宁,810008
2. 中国科学院青海盐湖研究所,青海,西宁,810008;中国科学院研究生院,北京,100039
3. 青海省岩矿测试应用研究所,青海,西宁,810008
摘    要:为准确、快速测定锂离子电池正极材料LiCoxMn2-xO4中锰、钴的含量,给出了一个快速、简便的测定方法。提出了用络合滴定法测定锰含量,返络合滴定法测定锰、钴总量,再利用差减法计算出钴含量。相关的进行了酸溶解选择试验、锰含量测定条件选择试验、总量测定指示剂选择试验。最后,对锂离子电池正极材料LiCo0 1Mnl 9O4中的锰、钴含量进行了测定,结果表明,具有较高的精密度和准确度。

关 键 词:LiCoxMn2-xO4  测定  锰含量  钴含量
文章编号:1008-858X(2005)02-0011-05
修稿时间:2004年11月19

Measurement of Manganese and Cobalt Content in Cathode Materials for Li- ion Batteries
RAN Guang-fen,ZHOU Yuan,MA Pei-hu,LIANG Tiao,WANG Ya-hong.Measurement of Manganese and Cobalt Content in Cathode Materials for Li- ion Batteries[J].Journal of Salt Lake Research,2005,13(2):11-15.
Authors:RAN Guang-fen  ZHOU Yuan  MA Pei-hu  LIANG Tiao  WANG Ya-hong
Abstract:In order to measure the content of the manganese and cobalt in the cathode material LiCo_(0.1)Mn_(1.9)O_4 for Li-ion Battery accurately and quickly, we conducted the experiments for the choice of the acidic dissolving agent. Complexometry was adopted to measure the content of manganese by the condition-selection experiment.The measurement of the total content of manganese and cobalt was by returns complexometry. Finally, we made use of subtraction to compute the content of cobalt. According to the accurate result in this paper, we conclude that it is a simple, prompt method of precision.
Keywords:Cathode material  Measurement  Content of maganese  Content of cobalt
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