| 甲壳胺对甲基丙烯酸溶液聚合的“模板”效应 |
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| 引用本文： | 柳向林,杨靖先,姜玲.甲壳胺对甲基丙烯酸溶液聚合的“模板”效应[J].中国海洋大学学报(自然科学版),1996(2). |
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| 作者姓名： | 柳向林 杨靖先 姜玲 |
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| 作者单位： | 化工部海洋涂料研究所 |
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| 基金项目： | 国家自然科学基金!29170184 |
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| 摘 要： | 研究甲壳胺（CTS）对甲基丙烯酸（MAA）水溶液聚合的影响，探讨在不同MAA／－NH2摩尔比的水溶液中MAA聚合形成聚合物的分子量和结构规整性，结果表明CTS对MAA聚合物的结构规整性有影响，即具有一定的“模板”效应。
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| 关 键 词： | 甲壳胺 甲基丙烯酸 聚甲基丙烯酸甲酯（PMMA） “模板”效应 |
STUDY OF "MATRIX EFFECT" OF CHITOSAN ON THE POLYMERIZATION OF METHACRYLIC ACID |
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| Liu Xianglin, Yang Jingxian, Jiang Ling.STUDY OF "MATRIX EFFECT" OF CHITOSAN ON THE POLYMERIZATION OF METHACRYLIC ACID[J].Periodical of Ocean University of China,1996(2). |
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| Authors: | Liu Xianglin Yang Jingxian Jiang Ling |
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| Institution: | Marine Chemistry Department |
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| Abstract: | In this paper, we study the effect of the macromolecular chain of chitosan (CTS) on the polymerization of methylacrylic acid (MAA) in aqueous solution.The molecular weight and tacticity of the polymer obtained from radical polymerization of MAA in aqueous sdlutins with different MAA/-NH2 molar ratios are also studied. The result demonstrates that CTS has some matrix effect (or macromolecular effect) on the tacticity of the polymer of MAA. |
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| Keywords: | chitosan methacyrlic acid polymethyl methacrylate matrix effect |
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