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Mantle source for Oldoinyo Lengai carbonatites: Evidence from helium isotopes in fumarole gases
Authors:AJ Teague  TM Seward  D Harrison
Institution:1. Institute for Mineralogy and Petrography, ETH Zurich, CH-8092, Switzerland;2. Institute for Isotope Geology and Mineral Resources, ETH Zurich, CH-8092, Switzerland;3. Department of Earth Sciences, University of Bristol, BS8 1RJ, UK
Abstract:Oldoinyo Lengai is the world's only active carbonatite volcano and considerable debate still surrounds the genesis of its magmas. Gases were collected from two fumaroles discharging close to the then active vent in October 2003. Measured fumarole temperatures were ≤ 195°C, despite the nearby, vigorous eruptive activity. Gases were sampled and analysed for noble gas isotopes. Freshly erupted natrocarbonatite lavas, a 1917 nephelinite and a sub-recent wollastonite bearing rock were also collected and analysed for noble gas isotopes using vacuum crushing techniques. In all the lava samples the neon, argon, krypton and xenon isotope ratio data are indistinguishable from air implying atmospheric contamination of the hygroscopic rocks. In the fumaroles, measured 3He/4He ratios are between 4 and 7 R/Ra. This range is similar to published values for silicate xenoliths of the East African Rift implying a local lithospheric mantle source for the volatile component of the Lengai magmas. It is still unclear if the natrocarbonatites themselves come from this region, or if fractionation and/or liquid immiscibility generate the carbonate magmas from a silicate melt within the crust itself.
Keywords:Oldoinyo Lengai  volcanic gases  noble gas isotopes  mantle volatiles
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