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Early stage incorporation of biolipids into kerogen in a lacustrine sediment: Evidence from alkaline potassium permanganate oxidation of sedimentary lipids and humic matter
Authors:Ryoshi Ishiwatari  Tsutomu Machihara
Abstract:Lipids, fulvic acid, humic acid and kerogen were isolated from a lacustrine sediment in which the organic matter is probably derived predominantly from phytoplankton (Lake Haruna, Japan). An alkaline KMnO4 oxidation study of the organic matter showed that distributions of polymethylene chain lengths in the lipids, humic acid and kerogen fractions are almost the same. The polymethylene chains in the sediment are dominant in the kerogen, lipids and humic acid, their relative abundance estimated by the oxidation being: kerogen (42% of the total amounts of polymethylene chains estimated) > lipids (38%) > humic acid (19%) > fulvic acid (1%). It was concluded that algal lipids may have been incorporated into the kerogen and humic acid fractions after the death of the algae and during, after, their deposition.
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