Kinetics of the Reactions of IO with HO2 and O(3P) |
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| Authors: | Carlos E Canosa-mas Mark L Flugge Dina Shah Alison Vipond Richard P Wayne |
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| Institution: | (1) Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Rd., Oxford, OX1 3QZ, UK |
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| Abstract: | A discharge-flow tube coupled with resonance fluorescence and chemiluminescence detection has been used to investigate the reactions IO + HO2  products (1) and IO + O(3P) I + O2(2), at T = 296 ± 1 K and P = 1.7 - 2 Torr. The rate constants k-1 and k2 have been found to be (7.1 ± 1.6) × 10-11 cm3 molecule-1 s-1 and (1.35 ± 0.15) × 10-10 cm3 molecule-1 s-1, respectively. |
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| Keywords: | iodine IO HO2 O(3P) discharge-flow resonance fluorescence |
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