| 非离子表面活性剂修饰纳米钛柱撑粘土材料的合成与应用 |
| |
| 引用本文： | 安太成,丁雪军,陈江耀,李桂英,陈嘉鑫,傅家谟,盛国英.非离子表面活性剂修饰纳米钛柱撑粘土材料的合成与应用[J].矿物岩石地球化学通报,2011,30(1):53-58. |
| |
| 作者姓名： | 安太成 丁雪军 陈江耀 李桂英 陈嘉鑫 傅家谟 盛国英 |
| |
| 作者单位： | 1. 中国科学院,广州地球化学研究所有机地球化学国家重点实验室,广东省环境资源利用与保护重点实验室,广州,510640
2. 中国科学院,广州地球化学研究所有机地球化学国家重点实验室,广东省环境资源利用与保护重点实验室,广州,510640;中国科学院,研究生院,北京,100049 |
| |
| 基金项目： | 国家自然科学基金资助项目(40302013,40572173和40632012) |
| |
| 摘 要： | 本文采用非离子表面活性剂聚乙烯醇(PVA)对粘土进行改性修饰,并以钛酸丁酯和盐酸分别为前驱物和酸催化剂,采用溶胶-凝胶法制备了PVA修饰疏水型纳米钛柱撑粘土材料,对其进行了比表面积(BET)、热重分析(TGA)、X射线粉末衍射(XRD)和扫描电子显微镜(SEM)表征。实验结果表明,TiO2成功地插入了粘土层间,并以锐钛矿型的晶型存在,制备的柱撑粘土复合材料仍有较好的层状结构,其比表面积较原土有明显的增加,经过PVA修饰后柱撑粘土表面的疏水性得到了提高。以甲基橙的吸附和降解为模型反应,考察了柱撑粘土的吸附性能和光催化活性,实验结果发现PVA修饰疏水型纳米钛柱撑粘土材料对甲基橙表现出了良好的吸附能力和较好的光催化活性。
|
| 关 键 词： | 柱撑粘土 非离子表面活性剂 吸附 光催化 甲基橙 |
Synthesis and Application of Hydrophobic TiO2 Pillared Clay Modified by Non-ionic Surfactant |
| |
| AN Tai-cheng,DING Xue-jun,CHEN Jiang-yao,LI Gui-ying,CHEN Jia-xin,FU Jia-mo,SHENG Guo-ying.Synthesis and Application of Hydrophobic TiO2 Pillared Clay Modified by Non-ionic Surfactant[J].Bulletin of Mineralogy Petrology and Geochemistry,2011,30(1):53-58. |
| |
| Authors: | AN Tai-cheng DING Xue-jun CHEN Jiang-yao LI Gui-ying CHEN Jia-xin FU Jia-mo SHENG Guo-ying |
| |
| Institution: | AN Tai-cheng1,DING Xue-jun1,2,CHEN Jiang-yao1,LI Gui-ying1,CHEN Jia-xin1,FU Jia-mo1,SHENG Guo-ying11.State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Resources Utilization and Protection,Guangzhou Institute of Geochemistry,Chinese Academy of Sciences,Guangzhou 510640,China,2.Graduate School of Chinese Academy of Sciences,Beijing 100049 |
| |
| Abstract: | The surfactant modified TiO2 pillared clay was prepared by sol-gel method at certain ratio of tetra-n-butyl titanium to hydrochloric acid modified by non-ionic surfactant polyvinyl alcohol(PVA).Thermal gravity analysis(TGA),X-ray diffraction(XRD) and Scanning electron microscopy(SEM) were used to investigate the texture of the prepared catalyst,and its BET surface area was also measured.The results indicated that PVA-modified TiO2 pillared clay was well pillared by the anatase TiO2 and the BET surface area ... |
| |
| Keywords: | pillared clay non-ionic surfactant adsorption photocatalytic methyl orange |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
