The impact of organic fluids on the carbon isotopic compositions of carbonate-rich reservoirs: Case study of the Lucaogou Formation in the Jimusaer Sag,Junggar Basin,NW China |
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| Institution: | 1. State Key Laboratory for Mineral Deposits Research, Department of Earth Sciences, Nanjing University, Nanjing, Jiangsu 210023, PR China;2. PetroChina Xinjiang Oilfield Company, Karamay, 834000, PR China;1. State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum, Beijing 102249, China;2. Department of Earth Sciences, Durham University, South Road, Durham, DH1 3LE, UK;1. State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum, Beijing 102249, China;2. Exploration & Production Research Institute SINOPEC, Beijing 100083, China;3. Shandong Provincial Key Laboratory of Depositional Mineralization & Sedimentary Mineral, Shandong University of Science and Technology, Qingdao, Shandong 266590, China;1. State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum, Beijing, 102249, China;2. College of Geosciences, China University of Petroleum, Beijing, 102249, China;3. Department of Geology and Geophysics, Texas A&M University, College Station, TX 77843-3115, USA;4. Songyuan Gas Production Plant in Jilin Oil?eld Company, PetroChina, Songyuan, 138000, China;5. PetroChina Xinjiang Oilfield Company, Karamay, 834000, China |
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| Abstract: | The processes involved in the interaction between organic fluids and carbonates, and the resulting effect on reservoir quality during the evolution and maturation of organic matter remain unclear despite the fact that these processes influence the carbon and oxygen isotopic compositions of carbonates. Here, we provide new insights into these processes using data obtained from a detailed analysis of a mixed dolomitic–clastic and organic-rich sedimentary sequence within the middle Permian Lucaogou Formation in the Junggar Basin of NW China. The techniques used during this study include drillcore observations, thin section petrography, scanning electron microscopy (SEM) and electron probe microanalysis, and carbon and oxygen isotope analyses. Oil grades and total organic carbon (TOC) contents represent the amount of oil charging and the abundance of organic fluids within a reservoir, respectively, and both negatively correlate with the whole-rock δ13C and δ18O of the carbonates in the study area, indicating that organic fluids have affected the reservoir rocks. Secondary carbonates, including sparry calcite and dolomite overgrowths and cements, are common within the Lucaogou Formation. Well-developed sparry calcite is present within dark mudstone whereas the other two forms of secondary carbonates are present within the dolomite-rich reservoir rocks in this formation. Comparing thin section petrology with δ13C compositions suggests that the carbon isotopic composition of matrix carbonates varies little over small distances within a given horizon but varies significantly with stratigraphic height as a result of the development of secondary carbonates. The net change in whole-rock δ13C as a result of these secondary carbonates ranges from 1.8‰ to 4.6‰, with the secondary carbonates having calculated δ13C compositions from ?18.6‰ to ?8.5‰ that are indicative of an organic origin. The positive correlation between the concentration of Fe within matrix and secondary carbonates within one of the samples suggests that the diagenetic system within the Lucaogou Formation was relatively closed. The correlation between δ13C and δ18O in carbonates is commonly thought to be strengthened by the influence of meteoric water as well as organic fluids. However, good initial correlation between δ13C and δ18O of whole rock carbonates within the Lucaogou Formation (resulted from the evaporitic sedimentary environment) was reduced by organic fluids to some extent. Consequently, the δ13C–δ18O covariations within these sediments are not always reliable indicators of diagenetic alteration by organic fluids or meteoric water.The characteristics and δ13C compositions of the sparry calcite within the formation is indicative of a genetic relationship with organic acids as a result of the addition of organic CO2 to the reservoir. Further analysis suggests that both carbonate and feldspar were dissolved by interaction with organic CO2. However, dissolved carbonate reprecipitated as secondary carbonates, meaning that the interaction between organic fluids and dolomites did not directly improve reservoir quality, although this process did enhance the dissolution of feldspar and increase porosity. This indicates that the δ13C and δ18O of secondary carbonates and their influence on whole-rock carbonate isotopic values can be used to geochemically identify the effect of organic fluids on closed carbonate-rich reservoir systems. |
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| Keywords: | Impact of organic fluids Carbon isotopic compositions Carbonate-rich reservoirs Secondary carbonates Closed diagenetic system The Lucaogou Formation Jimusaer Sag |
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