| 伯胺N1923氯仿萃取盐酸振荡反应的量热法研究 |
| |
| 引用本文： | 于秀芳,张洪林,李向阳.伯胺N1923氯仿萃取盐酸振荡反应的量热法研究[J].盐湖研究,2003,11(1):59-61. |
| |
| 作者姓名： | 于秀芳 张洪林 李向阳 |
| |
| 作者单位： | 1. 曲阜师范大学化学系,山东,曲阜,273165
2. 山东威海进出口商品检验检疫局,山东,威海,26400 |
| |
| 摘 要： | 在不同温度和酸度时 ,利用滴定微量量热法测定了伯胺N192 3 氯仿液萃取盐酸的振荡反应体系的热功率 -时间曲线 ,根据获得的振荡诱导期 (tin) ,,第一振荡周期 (tp.l)的数据 ,计算了表现活化能和反应级数 ,建立了下列关系式 :tin∝c0 14 72 exp(1 3 48.6T ) tp .1∝c0 2 413 exp(4 3 3 1 .4T )
|
| 关 键 词： | 萃取振荡反应 伯胺N1923 盐酸 滴定微量量热法 |
| 文章编号： | 1008-858X(2003)01-0059-03 |
| 修稿时间： | 2002年9月16日 |
Microcalorimetric Study of the Extraction Oscillation System for the Extraction of Hydrochloric Acid With Primary Amine N1923 in Chloroform |
| |
| YU Xiu-fang,ZHANG Hong-lin,LI Xiang-yang.Microcalorimetric Study of the Extraction Oscillation System for the Extraction of Hydrochloric Acid With Primary Amine N1923 in Chloroform[J].Journal of Salt Lake Research,2003,11(1):59-61. |
| |
| Authors: | YU Xiu-fang ZHANG Hong-lin LI Xiang-yang |
| |
| Institution: | YU Xiu-fang 1,ZHANG Hong-lin 1,LI Xiang-yang 2 |
| |
| Abstract: | The power-time curves of the extraction oscillation system were determined at different temperatures for the extraction of hydrochloric acid with primary amine N 1923 in chloroform,using the titration microcalorimetric method.The apparent activation energy and reaction orders were calculated,from the induction period( t in ) and the first oscillation period ( t p.l ) The following relationship were established: t in∝ c 0.1472 exp(1348.6 T ), t p.1∝ c 0.2413 exp(4331.4 T ). |
| |
| Keywords: | Extraction oscillation system Primary amine N1923 Hydrochloric acid Titration microcalorimetric method |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《盐湖研究》浏览原始摘要信息 |
| 点击此处可从《盐湖研究》下载免费的PDF全文 |
