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Oxidation inhibitors occuring in bioproducers, recent sediments, ancient rocks and oils
Authors:Valentina N Burkova  Svetlana I Pisareva
Abstract:Native antioxidants (AO) are involved in the transformation of organic matter (OM) in different stages of diagenesis. In the early stages, the geochemical significance of AO can be estimated by using AO consumption index (I). The positive I values suggest that the OM fossilization proceeded under reducing conditions which favoured the formation of oil-source rocks, while the negative I values indicate oxidizing conditions which are characterized by the formation of rocks having a low oil-generation potential. In the late stages of diagenesis, the AO content is indicative of the degree of catagenic (thermal) or biodegradation (oxidative) transformation of oils. The AO contents of Paleogenic, Mesozoic and Paleozoic oils have been found to differ approximately by one order of magnitude. A major portion of AO is concentrated in oil resins and asphaltenes. The ratio of AO to resins and asphaltenes can be used as criterion of catagenic transformation of OM.
Keywords:antioxidants  orginal organisms  recent sediments  ancient rocks  oil
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