| CuCl2—石墨层间化合物的结构及电化学性能研究 |
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| 引用本文： | 龙光明,康永峰.CuCl2—石墨层间化合物的结构及电化学性能研究[J].盐湖研究,2000,8(2):16-21. |
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| 作者姓名： | 龙光明 康永峰 |
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| 作者单位： | 中国科学院青海盐湖研究所西安二部!陕西西安710043 |
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| 摘 要： | 用直接反应法制备了C/CuCl2 从 6 .3- 88.2的五种不同的CuCl2 -石墨层间化合物 .X射线粉末衍射分析指出它们分别为一阶、一二混阶、二阶和高阶 (大于二阶 )石墨层间化合物 ,Ic(°A)分别为 9.4 6、9.4 6 /11.6 3、12 .0 99、15.74、18.394 °A。通过循环伏安法对一阶、一二混阶层间化合物的电化学性能进行了研究 ,并测试了作为锂电池阴极材料的电池充放电循环性能
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| 关 键 词： | CuCl_2-石墨层间化合物 XRD 循环伏安法 锂电池阴极材料 |
| 修稿时间： | ： 1999-09- |
Study on the Structure and Electrochemical Properties of Graphite-CuCl_2 Intercalation Compounds |
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| WTBZLONG Guang ming,KANG Yong feng WTBX.Study on the Structure and Electrochemical Properties of Graphite-CuCl_2 Intercalation Compounds[J].Journal of Salt Lake Research,2000,8(2):16-21. |
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| Authors: | WTBZ]LONG Guang ming KANG Yong feng [WTBX] |
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| Institution: | WT5BZ]LONG Guang ming,KANG Yong feng [WT5BX] |
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| Abstract: | WT5BZ]Five graphite-CuCl 2 intercalation compounds with different compositions were formed by directly reacting with graphite and CuCl 2·2H 2O. They were indicated to be 1、1 2、2、3 stages respectively and have Ic°A of 9.46、9.46/11.63、12.09、14.94、18.39 by XRD. Their stabilities in air、 water、 NH 3(aq)、 EtOH、PC were examined. Their circle V-A curves gave some information about their electrochemical properties, when two of them, with 1 and 1 2 stages, were used as cathode material in LiClO 4-PC non aqueous systems. The ability of recharging of the Li-cell with Cu 2 used as cathode material was tested, which showed gave a good result. WT5HZ] |
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| Keywords: | CuCl 2 -graphite intercalation compounds XRD Cicle V-A curves Li-cell |
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