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Italian zeolitized rocks of technological interest
Authors:M de'Gennaro  A Langella
Institution:(1) Istituto Policattedra di Scienze Geologico-Mineralogiche, Facoltà di Scienze, Università di Sassari, Corso G.M. Angioj 10, 70100 Sassari, Italy;(2) Dipartimento di Scienze della Terra, Facoltà di Scienze, Università di Napoli ldquoFederico IIrdquo, Via Mezzocannone 8, 80134 Napoli, Italy
Abstract:Large areas of Italian territory are covered by thick and widespread deposits of zeolite-bearing volcaniclastic products. The main zeolites are phillipsite and chabazite spread over the whole peninsula, and clinoptilolite recorded only in Sardinia. A trachytic to phonolitic glassy precursor accounts for the formation of the former zeolites characterized by low Si/Al ratios (les3.00), while clinoptilolite is related to more acidic volcanism. The genesis of most of these zeolitized deposits is linked to pyroclastic flow emplacement mechanisms characterized by quite high temperatures and by the presence of abundant fluids. The main utilization of these materials has been and still is as dimension stones in the building industry. Currently, limited amounts are also employed in animal farming (dietary supplement, pet litter and manure deodorizer) and in agriculture as soil improvement and slow-release fertilizers. New fields of application have been proposed for these products on account of their easy availability, very low cost, their high-grade zeolites (50–70%), and good technological features such as high cation exchange capacities and adsorption properties.
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