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Removal of NO3– from Drinking Water by Electrocoagulation – An Alternate Approach
Authors:Subramanyan Vasudevan  Florence Epron  Jothinathan Lakshmi  Subbiah Ravichandran  Swaminathan Mohan  Ganapathy Sozhan
Institution:1. Laboratoire de Catalyse en Chimie Organique, Universite de Poitiers, CNRS, Poitiers, France.;2. Central Electrochemical Research Institute (CSIR), Karaikudi, India.
Abstract:The present study provides an electrocoagulation method, for the removal of NO3from drinking water using magnesium as the anode and cathode. The experiments are carried out as a function of pH, temperature, and current density. The results show that the maximum removal efficiency of 95.8% was achieved at a current density of 0.25 A/dm2, at a pH of 7.0. The adsorption of NO3preferably fitting the Langmuir adsorption isotherm suggests monolayer coverage of the adsorbed molecules. The adsorption process follows a second‐order kinetics model. Thermodynamic studies show that the adsorption was exothermic and spontaneous in nature.
Keywords:Adsorption kinetics  Clean technology  Electrocoagulation  Isotherms  NO3–  removal
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