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Blaubleibender covellite and its relationship to normal covellite
Authors:A Putnis  J Grace  W E Cameron
Institution:(1) Department of Mineralogy and Petrology, University of Cambridge, Downing Place, CB2 3EW Cambridge, England;(2) Department of Geology, Western Michigan University, 49008 Kalamazoo, Michigan, USA
Abstract:Both natural and synthetic samples of blaubleibender (blue-remaining) covellite have been studied by reflected light microscopy, electron probe microanalysis and electron microscopy and diffraction. The natural sample of composition Cu1.20S has a radic19a × radic19a superstructure based on the hexagonal coveilite subcell (side a). The synthetic sample of composition Cu1.10S has a 2radic7 a × 2 radic7a superstructure. In both cases the phases are homogeneous. The evidence suggests that the recognition of two distinct types of blaubleibender covellite may be an oversimplification, and that a series of metastable superstructures based on the covellite structure may exist.Work done while on leave at the Department of Mineralogy and Petrology, Cambridge
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