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闽西南十二排斑岩钼矿床地质特征、同位素年代学与岩石地球化学
引用本文:袁远,张达,潘天望,高彦华,李成远,倪建辉,韦牧.闽西南十二排斑岩钼矿床地质特征、同位素年代学与岩石地球化学[J].矿床地质,2019,38(5):1094-1116.
作者姓名:袁远  张达  潘天望  高彦华  李成远  倪建辉  韦牧
作者单位:中国地质大学地球科学与资源学院,北京,100083;福建省第八地质大队,福建龙岩,364000
基金项目:本文得到中国地质调查局地质调查(编号:12120113089600、12120114028701、1212011085472)项目和国家自然科学基金重点项目(编号:41530321)的联合资助
摘    要:十二排钼矿床位于上杭-云霄断裂带与闽西南拗陷的复合部位,是紫金山铜金矿田外围新近探明的一处具有中大型远景的斑岩型钼矿床。野外地质调查显示,其钼矿化呈细脉状、网脉状主要产出于黑云母二长花岗岩和黑云母花岗斑岩中。热液蚀变具有斑岩型矿床的分带特征,由黑云母花岗斑岩向外依次发育钾硅酸盐化带、绢英岩化带和青磐岩化带,钼矿体主要赋存于绢英岩化与钾硅酸盐化构成的叠加带中。锆石U-Pb定年结果表明,黑云母二长花岗岩和黑云母花岗斑岩分别形成于(143.1±0.9)Ma和(143.5±0.4)Ma。4件辉钼矿样品的Re-Os加权平均年龄为(143.9±2.1)Ma。辉钼矿的w(Re)为1.2×10~(-6)~7.8×10~(-6),说明成矿物质可能主要来自地壳。岩石地球化学分析结果显示,十二排含矿花岗岩具有相似的主量和微量元素组成,均属于弱过铝质高钾钙碱性I型花岗岩,其中,黑云母花岗斑岩表现出高分异花岗岩特征,两者可能是古老变质基底来源的熔体经历不同程度分异结晶的产物,并混入有少量幔源物质。综合已有的资料,文章认为十二排斑岩型钼矿化与早白垩世早期花岗质岩浆活动密切相关,上杭-云霄断裂带存在古太平洋板块俯冲后撤引发构造体制转换阶段的成岩成矿响应,进一步找矿勘查工作应加强评价早白垩世早期高分异花岗岩体的钼多金属成矿潜力。

关 键 词:地球化学  矿床地质特征  锆石U-Pb定年  辉钼矿Re-Os同位素年代学  斑岩型钼矿床  十二排  上杭-云霄  闽西南拗陷
收稿时间:2019/3/27 0:00:00
修稿时间:2019/7/6 0:00:00

Geology, geochronology and geochemistry of Shierpai porphyry molybdenite deposit in southwestern Fujian Province
YUAN Yuan,ZHANG D,PAN TianWang,GAO YanHu,LI ChengYuan,NI JiangHui and WEI Mu.Geology, geochronology and geochemistry of Shierpai porphyry molybdenite deposit in southwestern Fujian Province[J].Mineral Deposits,2019,38(5):1094-1116.
Authors:YUAN Yuan  ZHANG D  PAN TianWang  GAO YanHu  LI ChengYuan  NI JiangHui and WEI Mu
Institution:School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China,School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China,School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China,School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China,School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China,No. 8 Geological Party of Fujian Province, Longyan 364000, Fujian, China and No. 8 Geological Party of Fujian Province, Longyan 364000, Fujian, China
Abstract:The Shierpai Mo deposit, located at the intersection of the southwestern Fujian depression belt and the Shanghang-Yunxiao fault zone, is an newly discovered porphyry Mo deposit with a medium-to large-sized prospecting prospective in the periphery of the Zijinshan Cu-Au orefield. Field observations reveal that veinlets and stockworks Mo mineralization occur in the biotite monzogranite and biotite granite porphyry. The deposit has developed typical porphyry-type alteration zoning, with potassic, phyllic and propylitic alteration zones from biotite granite porphyry outward. Mo mineralization is mainly hosted in the phyllic alteration overprinting potassic zone. Zircon U-Pb dating of the biotite monzogranite and biotite granite porphyry yielded weighted mean ages of (143.1±0.9)Ma and(143.5±0.4)Ma, respectively. Four molybdenite samples yielded Re-Os weighted mean age of(143.1±5.5) Ma with w(Re) varying from 1.2×10-6 to 7.8×10-6, indicative of a crustal origin for the ore metals. Geochemical data show that the two ore-related granitic rocks have similar major and trace elemental compositions, belonging to weak peraluminous, high-K calc-alkaline I-type granites, whereas biotite granite porphyry has characteristics of a highly fractionated I-type granite. They were probably derived from partial melting of the Proterozoic basement rocks with addition of minor mantle components, and subsequently experienced variable degrees of fractional crystallization. Combined with the published data from the study area, the authors hold that the porphyry-type Mo mineralization was genetically linked with the emplacement of granitic rocks in the Shierpai deposit during the earliest Cretaceous. These data prove that the earliest Cretaceous magmatism and related mineralization occurred in the Shanghang-Yunxiao fault zone, probably in response to the tectonic regime transition triggered by the slab rollback of the paleo-Pacific Plate. The further prospecting exploration could strengthen the potential evaluation of Mo polymetallic mineralization for the Earliest Cretaceous highly fractionated granitoids in the study area.
Keywords:geochemistry  ore geology  zircon U-Pb dating  molybdenite Re-Os geochronology  porphyry Mo deposit  Shierpai  Shanghang-Yunxiao  southwestern Fujian Province
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