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Age and isotope geochemistry of the Archaean Pongola and Usushwana suites in Swaziland, southern Africa: a case for crustal contamination of mantle-derived magma
Authors:E Hegner  A Krner  AW Hofmann
Institution:

aMax-Planck-Institut für Chemie, Postfach 3060, 6500 Mainz F.R.G.

bInstitut für Geowissenschaften, Universität Mainz, Postfach 3980, 6500 Mainz F.R.G.

Abstract:The igneous rocks of the Pongola Supergroup (PS) and Usushwana Intrusive Suite (UIS) represent a case of late Archaean continental magmatism in the southeastern part of the Kaapvaal craton of South Africa and Swaziland.

U-Pb dating on zircons from felsic volcanic rocks of the PS yields a concordia intercept age of 2940 ± 22Ma that is consistent with a Sm-Nd whole rock age of 2934 ± 114Ma determined on the PS basalt-rhyolite suite. The initial εNd of?2.6 ± 0.9 is the lowest value so far reported for Archaean mantle-derived rocks. Rb-Sr whole rock dating of the PS yields a younger isochron age of 2883 ± 69Ma, which is not significantly different form the accepted U-Pb zircon age.

An internal (cpx-opx-plag-whole rock) isochron for a pyroxenite from the younger UIS yields an age of 2871 ± 30 Ma and initial 143Nd/144Nd that lies off the CHUR growth curve by εNd ?2.9 ± 0.2. However, Sm-Nd whole-rock data for the UIS yield an excessively high age of not, vert, similar 3.1 Ga that conflicts with firm geological evidence showing the UIS to be intrusive into the PS.

The negative deviations of initialεNd from the chondritic Nd evolution curve suggest significant contamination of the PS and UIS melts by older continental crust. A mixing process with continental crust after magma segregation is supported by a high initial 87Sr/86Sr ratio of0.703024 ± 24 for a clinopyroxene sample from a UIS pyroxenite, compared with an expected value of not, vert, similar 0.701 for the 2.9 Ga mantle. We therefore interpret the linear array of data points for the UIS gabbros as a mixing line between 2.87 Ga old magma and older continental crust.

Parallel LREE-enriched REE patterns, negative Nb-Ti anomalies, a distinctive and uniform ratio of Ti/Zrnot, vert, similar 46 and a narrow span of initial Nd indicate a common source for both the PS and UIS suites which is different from primitive mantle.

Keywords:
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