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湘西南石英脉型金矿矿物流体包裹体pH值和Eh值的估算
引用本文:吴湘滨,戴塔根,何绍勋.湘西南石英脉型金矿矿物流体包裹体pH值和Eh值的估算[J].大地构造与成矿学,1999,23(3):248-253.
作者姓名:吴湘滨  戴塔根  何绍勋
作者单位:中南工业大学地质系,湖南,长沙,410083
摘    要:以湘西南石英脉型金矿床为例,研究p H、Eh 估算值的结果表明利用围岩蚀变反应方程以及采用碱金属离子、卤素元素离子估算pH 值是不完善的。本文根据热力学原则( 相平衡、电价中和) 提出了矿物流体包裹体成分体系计算pH 估算值的方法,并且讨论了测试包裹体时气体成分外逸是影响pH 和Eh 估算值的主要因素之一。

关 键 词:pH、Eh估算值  矿物流体包裹体  石英脉型金矿
文章编号:1001-1552(1999)03-0248-06

pH AND Eh ESTIMATED VALUES OF FLUID INCLUSIONS FROM QUARTZ VEIN-TYPE GOLD DEPOSITS IN SOUTHWESTERN HUNAN
WU Xiang-bin,DAI Ta-gen,HE Shao-xun.pH AND Eh ESTIMATED VALUES OF FLUID INCLUSIONS FROM QUARTZ VEIN-TYPE GOLD DEPOSITS IN SOUTHWESTERN HUNAN[J].Geotectonica et Metallogenia,1999,23(3):248-253.
Authors:WU Xiang-bin  DAI Ta-gen  HE Shao-xun
Abstract:The quartz vein-type gold deposits in southwestern Hunan Province are taken as examples. Researching results of pH and Eh estimated values from quartz-fluid inclusions have illustrated that it is incomplete to use the altered reactions or the ions of alkali metals and brine elements. According on thermodynamic rules,we suggested a method for calculating pH estimated values on the composition system of fluid inclusions, analyzed the main factors affecting pH and Eh estimated values and discovered that Eh estimated values using the two methods may been applied to examine removal of gaseous composition outward inclusions.
Keywords:pH and Eh estimated values  fluid inclusions  quartz vein-type gold deposits
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