Pressure solution at grain-to-grain contacts |
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| Authors: | Pierre-Yves F Robin |
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| Institution: | Department of Geology and Erindale College, University of Toronto, Mississauga, Ontario, Canada |
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| Abstract: | Whereas much petrographic evidence for pressure solution, in sedimentary rocks has been accumulated since Sorby's work, its thermodynamic justification has never been clearly established, and has been challenged by some authors. Difficulties disappear when it is recognized that in the most general case migration of chemical components proceeds down chemical-potential gradients rather than down concentration gradients. Along a grain contact a chemical-potential gradient is produced by variations in contact pressure and by local variations in Helmholtz energy of the solid. For example, in a sand made up of even-sized spherical grains buried 500 m, the ratio of the diameter (D) of the grains to that of a spherical elastic contact circle (a) is D/a ～- 26. The chemical potential at the center of such an elastic contact is ～- 14kcal mol?1 higher than in surrounding pore water saturated with respect to quartz. For comparison, at a temperature of 30°C, saturation with respect to amorphous silica rather than quartz raises the chemical potential by only 1.6 kcal mol?1. If the diameter of the contact circle has enlarged to e.g. a = D/5, the chemical potential at its center is still 0.5 kcal mol ?1 greater than that of free quartz under hydrostatic pressure. The corresponding potential gradients are the driving force of pressure solution. The concept of pressure solution thus does not contradict any thermodynamic principle; in particular, it does not require that the chemical component of the solid have a smaller partial volume in solution than in the solid state. Petrographic and experimental evidence can therefore be accepted without reservation. |
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