我国油田水中Na、Ca、Mg的φ(Z/L,x)规律及其应用 |
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引用本文: | 张金来.我国油田水中Na、Ca、Mg的φ(Z/L,x)规律及其应用[J].地球化学,1983(4):347-356. |
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作者姓名: | 张金来 |
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作者单位: | 地质部石油地质综合大队一○一队 |
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摘 要: | Na^ , Ca^ and Mg^ are known to be the principal mineralizing cations in oil-field waters.Chemical controls on their activity and concentration are solubility, adsorption capacity and hydration which are dependent on the primary chemical bond parameters, such as ionic potential (Z/L)and dectronegativity (x). This paper aims at expounding the regularities governing the quantitative distribution of Na, Ca, and Mg in nil-field waters in terms of the variation of φ(Z/L, x). Our studies have shown that the log concentrations of Na, Ca and Mg in oil-field water shave a linear correlation ,vith their ionic potential and dectronegativity. Therefore, the concentrations of these cations must follow the φ(Z/L, x) regularity which has found ,vide application in the following aspects: (1) to define various types of nil-field water; (2) to define the distribution of oil-field and non-oil-field waters; and (3) to define the boundaries of hydrochemical vertical zonation.
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关 键 词: | 油田水 纳 钙 镁 φ(Z/L,x)规律 |
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