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我国油田水中Na、Ca、Mg的φ(Z/L,x)规律及其应用
引用本文:张金来.我国油田水中Na、Ca、Mg的φ(Z/L,x)规律及其应用[J].地球化学,1983(4):347-356.
作者姓名:张金来
作者单位:地质部石油地质综合大队一○一队
摘    要:Na^ , Ca^ and Mg^ are known to be the principal mineralizing cations in oil-field waters.Chemical controls on their activity and concentration are solubility, adsorption capacity and hydration which are dependent on the primary chemical bond parameters, such as ionic potential (Z/L)and dectronegativity (x). This paper aims at expounding the regularities governing the quantitative distribution of Na, Ca, and Mg in nil-field waters in terms of the variation of φ(Z/L, x). Our studies have shown that the log concentrations of Na, Ca and Mg in oil-field water shave a linear correlation ,vith their ionic potential and dectronegativity. Therefore, the concentrations of these cations must follow the φ(Z/L, x) regularity which has found ,vide application in the following aspects: (1) to define various types of nil-field water; (2) to define the distribution of oil-field and non-oil-field waters; and (3) to define the boundaries of hydrochemical vertical zonation.

关 键 词:油田水        φ(Z/L,x)规律
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