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Phase boundary between ilmenite and perovskite structures in MnGeO3 determined by in situ X-ray diffraction measurements
Authors:Daisuke Yamazaki  Eiji Ito  Yoshinori Tange  Takashi Yoshino  Shuangmeng Zhai  Hiroshi Fukui  Anton Shatskiy  Tomoo Katsura  Ken-ichi Funakoshi
Institution:(1) Institute for Study of the Earth’s Interior, Okayama University, Misasa Tottori, 682-0193, Japan;(2) Geodynamics Research Center, Matsuyama, Ehime, Japan;(3) Japan Synchrotron Radiation Research Institute, Sayo, Hyogo, Japan
Abstract:In situ X-ray observations of the phase transition from ilmenite to perovskite structure in MnGeO3 were carried out in a Kawai-type high-pressure apparatus interfaced with synchrotron radiation. The phase boundary between the ilmenite and perovskite structures in the temperature range of 700–1,400°C was determined to be P (GPa) = 16.5(±0.6) − 0.0034(±0.0006)T (°C) based on Anderson’s gold pressure scale. The Clapeyron slope, dP/dT, determined in this study is consistent with that for the transition boundary between the ilmenite and the perovskite structure in MgSiO3.
Keywords:MnGeO3            Ilmenite  Perovskite  High pressure and temperature  Phase boundary
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