The functional relation between ion concentration in water vapor chemistry and the bond parameter in quantum chemistry |
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| Authors: | Gu Hong-kan |
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| Institution: | (1) Institute of Oceanology, Chinese Academy of Sciences, 266071 Qingdao |
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| Abstract: | The functional relation between “water vapor chemistry” ion concentration and the “quantum chemistry” bond parameter is (I
z/Z)VN=1/(a+b/C)a=0.627,b=0.234,R=0.988,S=0.0721 whereI
z/Z is specific electron affinity constant (as hydration force),I
z is last ionization potential,Z is ion valence,V is ion volume,N is coordination number (as hydration number),C is ion concentration (μg/L) in condensed water of water vapor;R is correlation coefficient,S is standard deviation;a andb are constants. The corresponding correlation curve shows thatC has positive correlation toI
z/Z and negative correlation toVN.
Contribution No. 3068 from the Institute of Occanology, Chinese Academy of Sciences.
The project supported by the NSFC. |
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| Keywords: | Water vapor chemistry Gu's function |
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