Effects of composition and structure of alginates on adsorption of divalent metals |
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Authors: | Zheng Nai-yu Zhang Yan-xia Fan Xiao Han Li-jun |
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Institution: | (1) Institute of Oceanology, Chinese Academy of Sciences, 266071 Qingdao |
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Abstract: | Results of a series of experiments (on the adsorption of divalent metal ions by dried alginic acid, Na and Ca alginates of
different composition and block structure) conducted in this systematic study of the effects of the composition and structure
of alginates on the static adsorption equilibrium of divalent metal ions indicate that the properties of alginate adsorption
to divalent metal ions are highly different, depending not only on the cations used, but also on the form and structure of
the alginates. There is close correlation between the adsorption properties and the structure of the alginates. The selectivity
coefficient of Na alginate for Cd-Sr ion exchange tends to increase with the increase of theM/G ratio in alginate, whereas the adsorption capacity of Ca alginate for Cu2+ ion decrease with the increase of the G-block or the average length of the G-block
and the total adsorption capacity of alginic acid is found to vary in the same order as theF
MM(diad frequency) in alginate in the mixed solution of Sr2+, Ba2+ and Cd2+.
Contribution No. 2166 from the Institute of Oceanology, Chinese Academy of Sciences. |
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Keywords: | composition structure adsorption ion exchange divalent metal alginate seaweed |
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