Single and binary adsorption of lead and cadmium ions from aqueous solution using the clay mineral beidellite |
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| Authors: | Özlem Etci Nihal Bekta? M Salim Öncel |
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| Institution: | (1) Department of Environmental Engineering, Gebze Institute of Technology, 41400 Gebze, Turkey; |
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| Abstract: | Beidellite, a low-cost, locally available and natural mineral was used as an adsorbent for the removal of lead and cadmium
ions from aqueous solutions in batch experiments. The kinetics of adsorption process was tested for the pseudo first-order,
pseudo second-order reaction and intra-particle diffusion models. The rate constants of adsorption for all these kinetic models
were calculated. Comparison amongst the models showed that the sorption kinetics was best described by the pseudo second-order
model. Langmuir and Freundlich isotherm models were applied to the experimental equilibrium data for different temperatures.
The adsorption capacities (Q°) of beidellite for lead and cadmium ions were calculated from the Langmuir isotherm. It was found that adsorption capacity
was in the range of 83.3–86.9 for lead and 42–45.6 mg/g for cadmium at different temperatures. Thermodynamic studies showed
that the metal uptake reaction by beidellite was endothermic in nature. Binary metal adsorption studies were also conducted
to investigate the interactions and competitive effects in binary adsorption process. Based on the optimum parameters found,
beidellite can be used as adsorbent for metal removal processes. |
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