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Iron-Titanium Oxide Geothermometry and Petrogenesis of Lava Flows and Dykes from Mandla Lobe of the Eastern Deccan Volcanic Province, India
Authors:Mansoor Ahmad  JP Shrivastava  
Institution:aDepartment of Geology, University of Delhi, Delhi - 110 007
Abstract:Compositional studies on different forms of magnetite, ulvospinel, ilmenite and hematite mineral phases occurring in 37 lava flows and 6 dykes of the Mandla lobe are presented in this paper. Ilmenite (0001) in equilibrium with titanomanetite show high values of temperature of equilibration, ranging from 1172–974°C, for high alumina quartz normative tholeiitic lava flows of Chemical Type - A; 1129–1229°C for low alumina quartz normative tholeiitic lava flows of Chemical Type - B; 1283–1124°C for tholeiitic lava flows of Chemical Type - F and 1243°C and 99O°C for two diopside olivine normative tholeiite flows of Chemical Type D. High olivine normative flows of Chemical Type - G and H show 1095°C and 1092°C respectively. Whereas, high hypersthene normative tholeiite flow of Chemical me C shows temperature of 1187°C. Data plots disposition over iron-titanium oxide equilibration temperature vs – logfo2, diagram for Mandla lava flows and other parts of the Deccan (Igatpuri, Mahabaleshwer, Nagpur and Sagar areas) revealed that tholeiitic (evolved) basalt of the eastern Deccan volcanic province formed at high temperatures whereas, picritic (primitive) lavas of Igatpuri and tholeiitic basalt of Mahabaleshwar areas were formed at low temperatures. Mahabaleshwer basalts follow FMQ (fayalite-magnetite-quartz) buffer curve but, plots of the Mandla basalts lie above this curve indicating higher temperatures of crystallisation of ilmenite-titanomagnetite than that of the lava flows from other parts of Deccan 'Raps. The eastern Deccan Traps are most evolved types of lava as characterised by its low Mg-number and Ni content whereas, Igatpuri lava flows are picritic (primitive), having high Mg-number and Ni contents. Temperature vs FeO + Fe2O3 / FeO + Fe2O3 + MgO ratio data plots for Mandla and other Deccan lava flows and liquidus data for Hawaiian tholeiites, indicated that Igatpuri basalts lie parallel to the liquidus line of Hawaiian tholeiite but at lower temperatures. Large data plots of Mandla lava flows lie along the liquidus line of the Hawaiian lava. The highly vesicular nature of compound lava flows having large amount of volatile is responsible for low temperature values whereas, lava flows represented by high temperatures show high modal values of glass and opaque minerals.
Keywords:Ilmenite-magnetite  basalt  equilibration temperature  oxygen fugacity
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