Variability of carbon monoxide in the mars atmosphere |
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| Authors: | RT Clancy DO Muhleman BM Jakosky |
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| Institution: | Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, USA |
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| Abstract: | In January of 1982 we measured a microwave spectrum of CO in the Martian atmosphere utilizing the rotational J = 1 → 2 transition of CO. We have analyzed data and reanalyzed the microwave spectra of R. K. Kakar, J. W. Waters, and W. J. Wilson, (Science196, 1090–1091, 1977, measured in 1975) and J. C. Good and F. P. Schloerb, (Icarus47, 166–172, 1981 measured in 1980) in order to constrain estimates of the temporal variability of CO abundance in the Martian atmosphere. Our values of CO column density from the data of Karar et al., Good and Schloerb, and our own are 1.7 ± 0.9 × 1020, 3.0 ± 1.0 × 1020, and 4.6 ± 2.0 × 1020cm?2, respectively. The most recent estimate of CO column density from the 1967 infrared spectra of J. Connes, P. Connes, and J.P. Maillard, (Atlas de Spectres Infarouges de Venus, Mars, Jupiter, et Saturne, Editions due Centre National de la Recherche Scientifique, Paris, 1969), is 2.0 ± 0.8 × 1020 cm?2 (L.D.G. Young and A.T. Young, Icarus30, 75–79, 1977). The large uncertainties given for the microwave measurements are due primarily to uncertainty in the difference between the continuum brightness temperature and atmospheric temperatures of Mars. We have accurately calculated the variation among the observations of the continuum (surface) brightness temperature of Mars, which is primaroly a function of the observed aspect of Mars. A more difficult problem to consider is variability of global atmospheric temperatures among the observations, particularly the effects of global dust storms and the ellipticity of the orbit of Mars. The large bars accompanying our estimates of CO column density from the three sets of microwave measurements are primarily caused by an assumed uncertainty of ±10°K in our atmospheric temperature model due to possible dust in the atmosphere. A qualitative consideration of seasonal variability of global atmospheric temperatures among the measurements suggests that there is not strong evidence for variability of the column abundance of CO on Mars, although variability of 0–100% over a time scale of several years is allowed by the data set. The implication for the variability of Mars O2 is, crudely, a factor of two less. We found that the altitude distribution of CO in the atmosphere of Mars was not well constrained by any of the spectra, although our spectrum was marginally better fitted by an altitude increasing profile of CO mixing ratios. |
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