Study on the restitution coefficient of original total organic carbon for high mature marine source rocks |
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| Authors: | Qin Jianzhong Zheng Longju and Tenger |
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| Institution: | (1) Wuxi Research Institute of Petroleum Geology, RIPED, SINOPEC, Wuxi, 214151, China |
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| Abstract: | On the basis of the results of hydropyrolysis simulations for about 90 different types of immature to mature source rocks
selected from about 5 000 marine source rocks in China, along with the natural thermal evolution profiles, the following conclusions
were obtained. (1) Total organic carbon (TOC) content of excellent marine source rocks does not change obviously when Ro < 0.8% or Ro > 1.3%, and the residual TOC content is decreasing gradually with the maturity increase at 0.8% < Ro < 1.3%. (2) At the high-post mature stage (Ro > 1.3%), the decreased maximums of residual TOC content for the kerogen of sapropel (I), II1, and II are usually 40%, 32% and 24%, respectively, and their TOC restitution coefficient is, respectively, 1.68, 1.48 and
1.32. (3) Both the TOC decreasing amplitude and the restitution coefficient decrease gradually with the decrease of TOC content
for the source rocks with low organic matter abundance (usually 0.3% < TOC < 1.0%). The TOC restitution coefficients are,
respectively, 1.20 and 1.0, when 0.3% < TOC < 0.5% and TOC < 0.3%. (4) TOCres of solid bitumen and shale with high organic matter abundance (TOC > 30%) also require no restitution at the high mature
stage. Such kind of TOC restitution is further supported by the coincidence of the decrease of residual TOC with the decreasing
of S1 + S2 and the increasing of hydrocarbon quantity during the experimental simulation of hydrocarbon generation and expulsion for
marine source rocks (0.3% < TOC < 30%) in natural thermal evolution profiles.
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Translated from Earth Science—Journal of China University of Geosciences, 2007, 32(6): 853–860 译自: 地球科学—中国地质大学学报] |
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| Keywords: | marine source rock high-post mature TOC restitution coefficient |
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