The late-Paleozoic mafic volcanic rocks occurring in the surrounding areas of the Gonghe basin are distributed in the A’nyêmaqên ophiolite zone, Zongwulong tectonic zone and Kuhai-Saishitang volcanic zone. The mafic volcanics in the A’nyêmaqên zone formed an ancient ridge-centered hotspot around the Majixueshan OIB, the Kuhai-Saishitang mafic rocks consist of E-MORB and continental rift basalts and the Zongwulong volcanic rocks are enriched N-MORB. The regionally low Nb/U and Ce/Pb ratios reflect the influence of the OIB material on the mafic magma source. From geochemistry, spatial distribution and tectonic relationship of the mafic rocks, an ancient triple-junction centered at the Majixueshan can be inferred. The existence of the Kuhai-Saishitang aulacogen may have provided a tectonic channel for the Majixueshan OIB materials metasomatizing the magma source for the Zongwulong rocks. The formation of the triple-junction and the rifting of the Zongwulong zone have separated the orogens and massifs in the region.