The breakdown of potassium feldspar at high water pressures |
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| Authors: | Pauline Thompson Ian Parsons Colin M Graham Brian Jackson |
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| Institution: | (1) Department of Geology and Geophysics, University of Edinburgh, West Mains Road, Edinburgh, EH9 3JW, Scotland, GB;(2) The Royal Museum of Scotland, Chambers Street, Edinburgh, EH1 1JF, Scotland, GB |
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| Abstract: | The equilibrium position of the reaction between sanidine and water to form “sanidine hydrate” has been determined by reversal
experiments on well characterised synthetic starting materials in a piston cylinder apparatus. The reaction was found to lie
between four reversed brackets of 2.35 and 2.50 GPa at 450 °C, 2.40 and 2.59 GPa at 550 °C, 2.67 and 2.74 GPa at 650 °C, and
2.70 and 2.72 GPa at 680 °C. Infrared spectroscopy showed that the dominant water species in sanidine hydrate was structural
H2O. The minimum quantity of this structural H2O, measured by thermogravimetric analysis, varied between 4.42 and 5.85 wt% over the pressure range of 2.7 to 3.2 GPa and
the temperature range of 450 to 680 °C. Systematic variation in water content with pressure and temperature was not clearly
established. The maximum value was below 6.07 wt%, the equivalent of 1 molecule of H2O per formula unit. The water could be removed entirely by heating at atmospheric pressure to produce a metastable, anhydrous,
hexagonal KAlSi3O8 phase (“hexasanidine”) implying that the structural H2O content of sanidine hydrate can vary. The unit cell parameters for sanidine hydrate, measured by powder X-ray diffraction,
were a = 0.53366 (±0.00022) nm and c = 0.77141 (±0.00052) nm, and those for hexasanidine were a = 0.52893 (±0.00016) nm and c = 0.78185 (±0.00036) nm. The behaviour and properties of sanidine hydrate appear to be analogous to those of the hydrate
phase cymrite in the equivalent barium system. The occurrence of sanidine hydrate in the Earth would be limited to high pressure
but very low temperature conditions and hence it could be a potential reservoir for water in cold subduction zones. However,
sanidine hydrate would probably be constrained to granitic rock compositions at these pressures and temperatures.
Received: 6 May 1997 / Accepted: 2 October 1997 |
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