The effects of the geothermal gradient on amino acid racemization |
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| Authors: | Barry J Katz Christopher GA Harrison Eugene H Man |
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| Institution: | 1. Department of Chemistry, University of Miami, Coral Gables, FL 33124 U.S.A.;2. Division of Marine and Atmospheric Chemistry, University of Miami, Coral Gables, FL 33124 U.S.A. |
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| Abstract: | The “second region” of the kinetic curve for the racemization (epimerization) of isoleucine in foraminifera is defined from previously published data corrected for the thermal history experienced by the samples. These kinetic parameters are applied to racemization data from Deep Sea Drilling Project Sites 332A and 333 from the Deep Drill Valley, Mid-Atlantic Ridge, and Site 148 from the Aves Ridge, in order to determine whether there are any observable effects due to the geothermal gradient. The data for Site 148 clearly show an increase of temperature with depth. The data for the two sites of the Mid-Atlantic Ridge do not show this clear relationship. When bottom water temperature variations are taken into consideration, the effects of the geothermal gradient become apparent. Since the degree of racemization is dependent upon both age and temperature, a knowledge of the age of a sample places constraints upon its thermal history, and hence on the heat flow at the location since deposition of the sample. The crude heat flow models thus developed are compatible with present geologic and geophysical information. It appears probable that detailed heat flow models may be developed by improving analytical precision. |
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