Thermal histories of IVA iron meteorites from transmission electron microscopy of the cloudy zone microstructure |
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| Authors: | J I GOLDSTEIN J YANG P G KOTULA J R MICHAEL E R D SCOTT |
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| Institution: | 1. Department of Mechanical and Industrial Engineering, 313 Engineering Lab, University of Massachusetts, 160 Governors Drive, Amherst, Massachusetts 01003, USA;2. Materials Characterization Department, Sandia National Laboratories, P.O. Box 5800, MS 0886, Albuquerque, New Mexico 87185, USA;3. Hawai'i Institute of Geophysics and Planetology, University of Hawai'i, Honolulu, Hawai'i 96822, USA |
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| Abstract: | Abstract— We have measured the size of the high‐Ni particles in the cloudy zone and the width of the outer taenite rim in eight low shocked and eight moderately to heavily shocked IVA irons using a transmission electron microscope (TEM). Thin sections for TEM analysis were produced by a focused ion beam instrument. Use of the TEM allowed us to avoid potential artifacts which may be introduced during specimen preparation for SEM analysis of high Ni particles <30 nm in size and to identify microchemical and microstructural changes due to the effects of shock induced reheating. No cloudy zone was observed in five of the eight moderately to highly shocked (>13 GPa) IVA irons that were examined in the TEM. Shock induced reheating has allowed for diffusion from 20 nm to 400 nm across kamacite/taenite boundaries, recrystallization of kamacite, and the formation, in Jamestown, of taenite grain boundaries. In the eleven IVA irons with cloudy zone microstructures, the size of the high‐Ni particles in the cloudy zone increases directly with increasing bulk Ni content. Our data and the inverse correlation between cooling rate and high‐Ni particle size for irons and stony‐irons show that IVA cooling rates at 350‐200 °C are inversely correlated with bulk Ni concentration and vary by a factor of about 15. This cooling rate variation is incompatible with cooling in a metallic core that was insulated with a silicate mantle, but is compatible with cooling in a metallic body of radius 150 ± 50 km. The widths of the tetrataenite regions next to the cloudy zone correlate directly with high‐Ni particle size providing another method to measure low temperature cooling rates. |
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