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Pesticides Removal Using Conventional and Low‐Cost Adsorbents: A Review
Authors:Javad Zolgharnein  Ali Shahmoradi  Jahanbakhsh Ghasemi
Institution:1. Faculty of Science, Department of Chemistry, Arak University, Arak, Iran;2. Faculty of Science, Department of Chemistry, Khajeh‐Nasir Toosi University of Technology, Tehran, Iran
Abstract:Worldwide pesticide usage has increased dramatically during the last three decades, coinciding with changing practices and increasing by intensive agriculture. This widespread use of pesticides for agricultural and non‐agricultural purposes has resulted in the presence of their residues in various environmental matrices. The occurrence of pesticides and their metabolite transported in rivers, channels, lakes, sea, air, soils, groundwater, and even drinking water, proves the high risk of these chemicals to human health and the environment. Therefore, pesticide removal is of an increasing concern. In this study, a review of the published literature dealing with pesticides removal process is presented. Firstly, pesticide removal by conventional means is briefly considered. Secondly, the use of the low‐cost sorbent through biosorption process is discussed comprehensively. The effect of factors such as pH, contact time, sorbent dosage, initial pesticide concentration, and optimization of biosorption conditions is also discussed. Kinetic, thermodynamic, and mechanism studies are also given. This study shows that both microorganisms and other materials with biological origin like agricultural by‐products may be used to this end. There is a significant potential for pesticide uptake by the use of various pristine and especially modified biosorbents. In the case of living organisms used as removal agents, degradation may also play a role in the total removal observed.
Keywords:Biosorption  Isotherm  Kinetics  Pesticide  Thermodynamics
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