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渤海湾北部海域表层海水的表观铜络合容量
引用本文:江志华,马启敏,于志刚,张艳艳.渤海湾北部海域表层海水的表观铜络合容量[J].中国海洋大学学报(自然科学版),2005,35(3):455-458.
作者姓名:江志华  马启敏  于志刚  张艳艳
作者单位:1. 中国海洋大学,环境科学系,山东,青岛,266003
2. 中国海洋大学,海洋化学系,山东,青岛,266003
基金项目:国家自然科学基金项目 (40 1 360 2 0 )资助
摘    要:为给渤海湾北部海域重金属铜环境容量研究提供科学依据,采用阳极溶出伏安法对该海域12个站位表层海水样品的表观铜络合容量(ACuCC)和条件稳定常数(K)以及络合容量指数(CCI)进行了测定和计钟:。得到该海区表层海水的表观铜络合容量在228.0~673.4nmol/L之间,平均值为437.5nmol/L,条件稳定常数对数值(IgK)变化范围在7.41~8.84之间,平均值为7.89,络合容量指数在72.69%~92、92%之间,平均值为82.93%。表明该海域表层海水对重金属铜具有较强的络合能力。

关 键 词:络合容量    阳极溶出伏安法  渤海湾
文章编号:1672-5174(2005)03-455-04
修稿时间:2004年5月10日

Apparent Copper Complexation Capacity of Surface Seawater in the North of the Bohai Bay
JIANG Zhi-hua,MA Qi-min,YU Zhi-gang,ZHANG Yan-yan.Apparent Copper Complexation Capacity of Surface Seawater in the North of the Bohai Bay[J].Periodical of Ocean University of China,2005,35(3):455-458.
Authors:JIANG Zhi-hua  MA Qi-min  YU Zhi-gang  ZHANG Yan-yan
Institution:JIANG Zhi-hua 1,MA Qi-min 1,YU Zhi-gang 2,ZHANG Yan-yan 1
Abstract:Using anodic stripping voltammetry (ASV),the apparent copper complexation capacity (ACuCC), conditional stability constant (K) and the complexation capacity index (CCI) of 12 seawater samples collected in the North of Bohai Bay in 2003 were investigated and calculated. The ACuCC values in the area were between 228.0 and 673.4nmol/L, the mean value being 437.5nmol/L, the lgK values were between 7.41 and 8.84, with a mean of 7.89. The CCI values were between 72.69% and 92.92%, the mean being 82.93%. Which shows that there is a strong complexation ability for Copper in the North of Bohai Bay.
Keywords:complexation capacity  copper  anodic stripping voltammetry  the Bohai Bay
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