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Variability of aquatic chemistry in central Guizhou karst region, China
Authors:Bai Zhanguo  Wan Guojiang
Institution:(1) Chinese Agricultural Ministry Key Laboratory of Plant Nutrition Research, Institute of Soils and Fertilizers, Chinese Academy of Agricultural Sciences, 0100081 Beijing;(2) State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, 550002 Guiyang
Abstract:It is necessary to understand the aquatic chemical characteristics of natural surface fresh water for water quality assessment. The chemical data from different kinds of water in the central Guizhou karst area showed that spring water from carbonate rock cracks (crack-water) is of neutrality or meta-alkalinity and C] Ca II type. The amounts of all ions and the concentrations of HCO 3 - and Ca2+ were higher in the autumn than in the spring, the crack-water was influenced by the infiltration of surface water in the process of erosion and/or transportation with decreasing HCO 3 - and increasing pH, SO 4 2- , Cl-, K+ and Na+ during running in a certain distance on the land surface. In particular, the chemical compositions of the waters at Tianxingqiao (upper-stream), Shuiliandong (mid-waterfall) and Luoshuitan (down-pool) near the Huangguoshu Waterfall were much different from those of the crack-water. The concentrations of SO 4 2- , Na+, Fe3+ and NO 3 - varied closely with seasons. The CaCO3 deposited violently with CO2 release in the spring. In Lake Hongfeng the HCO 3 - /SO 4 2- equivalent ratios were only 2.1–2.4, but Ca2+ /Mg2+ up to 2.4-4.2. The Cl- concentration increased by a factor of 1 and Na+ by order of magnitude relative to the spring water. These indicated the increase in artificial pollutant discharge in the Lake Hongfeng watershed. In addition, porewater in the soils covering carbonate rocks belongs to strongly mineralized water. The obvious differences in water quality were controlled by carbonate deposition, sulphate mineralization and nitrogen fixation as well as ammonification. It is indicated that the chemical compositions in the waters from the karst region were unstable and changeable. This project was financially supported by the IFS of Sweden and by the National Natural Science Foundation of China.
Keywords:karst region  variability of aquatic chemistry  central Guizhou Plateau
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