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Infiltration of Aqueous Fluid and High Fluid: Rock Ratios During Greenschist Facies Metamorphism: A Discussion
Authors:WOOD  BERNARD J; GRAHAM  COLIN M
Institution:1Department of Geological Sciences, Northwestern University Evanston, Illinois 60201
2Grant Institute of Geology, University of Edinburgh Edinburgh EH9 3JW, Scotland
Abstract:Ferry's (1984) analysis of the biotite isograd in pelitic schistsof the Waterville Formation (south-central Maine, U.S.A.) ledto the conclusion that metamorphism had been caused by infiltrationof 1–2 rock volumes of aqueous fluid. We find that thisimportant observation is extremely sensitive to the assumedtemperature of metamorphism and to corresponding uncertaintiesin the thermodynamic data and solution assumptions. Uncertaintiesin the experimental calibrations of the geothermometers areon the order of ? 30?C. In addition, an analysis of the effectsof minor substituents on calcite-dolomite and garnet-biotitegeothermometers indicates that Ferry's (1980) temperatures areabout 40?C too low in the garnet zone. Correcting the phaseequilibria to higher temperatures by this latter amount lowersfluid:rock ratios by an order of magnitude to about 0?1:1. Sincesmall uncertainties have such great effects it is clearly importantto perform careful uncertainty analyses before using Ferry'sapproach to draw wide-ranging conclusions about fluid-rock interactions.Given a 40?C upward revision of temperature it is not necessaryto invoke pervasive infiltration of aqueous fluid as the majoragent of metamorphism. With these low fluid:rock ratios thewater source could reasonably be a thin sequence of underlyingmetapelites and/or the granitic intrusives which accompaniedthe Acadian orogeny.
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