4.4 billion years of crustal maturation: oxygen isotope ratios of magmatic zircon |
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| Authors: | J W Valley J S Lackey A J Cavosie C C Clechenko M J Spicuzza M A S Basei I N Bindeman V P Ferreira A N Sial E M King W H Peck A K Sinha C S Wei |
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| Institution: | (1) Department of Geology, University of Wisconsin, Madison, WI 53706, USA;(2) Department de Mineralogia Geotectonica, University Sao Paulo, Sao Paulo, Brazil;(3) Department of Geological Sciences, University of Oregon, Eugene, OR 97403, USA;(4) NEG-LABISE, Department of Geology, Federal University of Pernambuco, Recife, PE, 50670-000, Brazil;(5) Department of Geography and Geology, Illinois State University, Normal, IL 61790, USA;(6) Department of Geology, Colgate University, Hamilton, NY 13346, USA;(7) Virginia Polytechnic Inst., Blacksburg, VA, USA;(8) School of Earth and Space Sciences, University of Science and Technology of China, Hefei, Anhui, 230026, China;(9) Department of Geology, College of Wooster, Wooster, OH 44691, USA;(10) Department of Geology, University of Puerto Rico, Mayaguez, PR 00681-9017, USA |
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| Abstract: | Analysis of δ18O in igneous zircons of known age traces the evolution of intracrustal recycling and crust-mantle interaction through time.
This record is especially sensitive because oxygen isotope ratios of igneous rocks are strongly affected by incorporation
of supracrustal materials into melts, which commonly have δ18O values higher than in primitive mantle magmas. This study summarizes data for δ18O in zircons that have been analyzed from 1,200 dated rocks ranging over 96% of the age of Earth. Uniformly primitive to mildly
evolved magmatic δ18O values are found from the first half of Earth history, but much more varied values are seen for younger magmas. The similarity
of values throughout the Archean, and comparison to the composition of the “modern” mantle indicate that δ18O of primitive mantle melts have remained constant (±0.2‰) for the past 4.4 billion years. The range and variability of δ18O in all Archean zircon samples is subdued (δ18O(Zrc)=5–7.5‰) ranging from values in high temperature equilibrium with the mantle (5.3± 0.3‰) to slightly higher, more evolved
compositions (6.5–7.5‰) including samples from: the Jack Hills (4.4–3.3 Ga), the Beartooth Mountains (4.0–2.9 Ga), Barberton
(3.5–2.7 Ga), the Superior and Slave Provinces (3.0 to 2.7 Ga), and the Lewisian (2.7 Ga). No zircons from the Archean have
been analyzed with magmatic δ18O above 7.5‰. The mildly evolved, higher Archean values (6.5–7.5‰) are interpreted to result from exchange of protoliths with
surface waters at low temperature followed by melting or contamination to create mildly elevated magmas that host the zircons.
During the Proterozoic, the range of δ18O(Zrc) and the highest values gradually increased in a secular change that documents maturation of the crust. After ∼1.5 Ga,
high δ18O zircons (8 to >10‰) became common in many Proterozoic and Phanerozoic terranes reflecting δ18O(whole rock) values from 9 to over 12‰. The appearance of high δ18O magmas on Earth reflects nonuniformitarian changes in the composition of sediments, and rate and style of recycling of surface-derived
material into magmas within the crust.
Electronic Supplementary Material Supplementary material is available for this article at |
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