Photooxidation of dimethyl sulfide and dimethyl disulfide. I: Mechanism development |
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Authors: | Fangdong Yin Daniel Grosjean John H Seinfeld |
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Institution: | (1) Department of Chemical Engineering, California Institute of Technology, Pasadena, CA, U.S.A. |
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Abstract: | Detailed theoretical (Part I, this article) and experimental (Part II) investigations are presented for the mechanism of the atmospheric photooxidation of dimethyl sulfide (CH3SCH3) and dimethyl disulfide (CH3SSCH3). In this paper, comprehensive mechanisms for the atmospheric chemistry of CH3SCH3 and CH3SSCH3 are developed based on fundamental considerations of all available kinetic and mechanistic information. |
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Keywords: | Dimethyl sulfide dimethyl disulfide photooxidation mechanism |
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