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The impact of high altitude aircraft on the ozone layer in the stratosphere
Authors:Xue Xi Tie  Guy Brasseur  Xing Lin  Pierre Friedlingstein  Claire Granier  Philip Rasch
Institution:(1) National Center for Atmospheric Research, 80307-3000 Boulder, CO, USA;(2) NOAA/ERL, Aeronomy Laboratory, 80303 Boulder, CO, USA;(3) National Center for Atmospheric Research, 80307-3000 Boulder, CO, USA
Abstract:The paper discusses the potential effects on the ozone layer of gases released by the engines of proposed high altitude supersonic aircraft. The major problem arises from the emissions of nitrogen oxides which have the potential to destroy significant quantities of ozone in the stratosphere. The magnitude of the perturbation is highly dependent on the cruise altitude of the aircraft. Furthermore, the depletion of ozone is substantially reduced when heterogeneous conversion of nitrogen oxides into nitric acid on sulfate aerosol particles is taken into account in the calculation. The sensitivity of the aerosol load on stratospheric ozone is investigated. First, the model indicates that the aerosol load induced by the SO2 released by aircraft is increased by about 10–20% above the background aerosols at mid-high latitude of the Northern Hemisphere at 15 km for the NASA emission scenario A (the NASA emission scenarios are explained in Tables I to III). This increase in aerosol has small effects on stratospheric ozone. Second, when the aerosol load is increased following a volcanic eruption similar to the eruption of El Chichon (Mexico, April 1982), the ozone column in spring increases by as much as 9% in response to the injection of NO x from the aircraft with the NASA emission scenario A. Finally, the modeled suggests that significant ozone depletion could result from the formation of additional polar stratospheric clouds produced by the injection of H2O and HNO3 by the aircraft engines.
Keywords:High altitude aircraft  stratospheric ozone layer  aerosol effect  heterogeneous chemistry
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