A review of coal properties pertinent to carbon dioxide sequestration in coal seams: with special reference to Victorian brown coals |
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| Authors: | M S A Perera P G Ranjith S K Choi A Bouazza J Kodikara and D Airey |
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| Institution: | (1) Department of Civil Engineering, Monash University, Building 60, Melbourne, VIC, 3800, Australia;(2) Division of Earth Science and Resource Engineering, Commonwealth Scientific and Industrial Research Organisation (CSIRO), Clayton, VIC, 3168, Australia;(3) School of Civil Engineering, University of Sydney, Sydney, NSW, 2006, Australia; |
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| Abstract: | This paper presents reviews of studies on properties of coal pertinent to carbon dioxide (CO2) sequestration in coal with specific reference to Victorian brown coals. The coal basins in Victoria, Australia have been
identified as one of the largest brown coal resources in the world and so far few studies have been conducted on CO2 sequestration in this particular type of coals. The feasibility of CO2 sequestration depends on three main factors: (1) coal mass properties (chemical, physical and microscopic properties), (2)
seam permeability, and (3) gas sorption properties of the coal. Firstly, the coal mass properties of Victorian brown coal
are presented, and then the general variations of the coal mass properties with rank, for all types of coal, are discussed.
Subsequently, coal gas permeability and gas sorption are considered, and the physical factors which affect them are examined.
In addition, existing models for coal gas permeability and gas sorption in coal are reviewed and the possibilities of further
development of these models are discussed. According to the previous studies, coal mass properties and permeability and gas
sorption characteristics of coals are different for different ranks: lignite to medium volatile bituminous coals and medium
volatile bituminous to anthracite coals. This is important for the development of mathematical models for gas permeability
and sorption behavior. Furthermore, the models have to take into account volume effect which can be significant under high
pressure and temperature conditions. Also, the viscosity and density of supercritical CO2 close to the critical point can undergo large and rapid changes. To date, few studies have been conducted on CO2 sequestration in Victorian brown coal, and for all types of coal, very few studies have been conducted on CO2 sequestration under high pressure and temperature conditions. |
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